一、電子陶瓷是絕緣體還是導體
一(yi)般認(ren)為(wei),陶瓷(ci)是良好的絕緣體(ti)(ti),它一(yi)般不導(dao)(dao)電(dian),因為(wei)原子(zi)的外層電(dian)子(zi)通常受到(dao)原子(zi)核的吸引力,被束縛在(zai)各自(zi)原子(zi)的周圍,不能自(zi)由運動,不過電(dian)子(zi)陶瓷(ci)具有極為(wei)寬廣(guang)的電(dian)氣特性,從一(yi)般的絕緣體(ti)(ti),到(dao)半導(dao)(dao)體(ti)(ti),導(dao)(dao)體(ti)(ti)、甚至超導(dao)(dao)體(ti)(ti),都有不同的電(dian)子(zi)陶瓷(ci)產品(pin)。
電(dian)子陶(tao)(tao)(tao)瓷(ci)(ci)(ci)(ci)(ci)的種類眾(zhong)多(duo),其中絕緣陶(tao)(tao)(tao)瓷(ci)(ci)(ci)(ci)(ci)裝置瓷(ci)(ci)(ci)(ci)(ci)和介(jie)電(dian)陶(tao)(tao)(tao)瓷(ci)(ci)(ci)(ci)(ci)是絕緣體,半導體陶(tao)(tao)(tao)瓷(ci)(ci)(ci)(ci)(ci)是半導體,離子陶(tao)(tao)(tao)瓷(ci)(ci)(ci)(ci)(ci)是導體,還有一種超(chao)導陶(tao)(tao)(tao)瓷(ci)(ci)(ci)(ci)(ci)屬(shu)于超(chao)導體。
二、電子陶瓷導電原理是什么
電子陶瓷有的導電,有的不導電,導電的電子陶瓷一般是通過一定的工藝處(chu)理,使其具有導電(dian)功能的。
某些氧化物陶(tao)瓷加熱時,處于原(yuan)子外層的電(dian)子可(ke)以(yi)獲得足夠的能量,以(yi)便克服原(yuan)子核對它(ta)的吸引力(li),而成為可(ke)以(yi)自由運(yun)動的自由電(dian)子,這種(zhong)陶(tao)瓷就(jiu)變成導(dao)電(dian)陶(tao)瓷。
一(yi)般當(dang)電(dian)(dian)(dian)(dian)流通過材料時,電(dian)(dian)(dian)(dian)子可以有兩種方(fang)式通過晶格運動(dong)來完(wan)成(cheng)電(dian)(dian)(dian)(dian)荷(he)輸運過程:①電(dian)(dian)(dian)(dian)子脫離(li)原(yuan)子成(cheng)為自由電(dian)(dian)(dian)(dian)子,在晶格中運動(dong),形成(cheng)所謂(wei)的(de)電(dian)(dian)(dian)(dian)子導電(dian)(dian)(dian)(dian);②電(dian)(dian)(dian)(dian)子與原(yuan)子核一(yi)起移(yi)動(dong)產生(sheng)所謂(wei)的(de)離(li)子導電(dian)(dian)(dian)(dian)。對金屬來說,電(dian)(dian)(dian)(dian)子導電(dian)(dian)(dian)(dian)是(shi)其導電(dian)(dian)(dian)(dian)的(de)主要(yao)方(fang)式,相比(bi)之下,離(li)子導電(dian)(dian)(dian)(dian)幾乎(hu)可忽略不(bu)計;但對于(yu)導電(dian)(dian)(dian)(dian)電(dian)(dian)(dian)(dian)子陶瓷(ci)來說,由于(yu)離(li)子電(dian)(dian)(dian)(dian)導活化(hua)能比(bi)較低(一(yi)般在0.5eV以下),離(li)子導電(dian)(dian)(dian)(dian)已不(bu)容忽視,是(shi)電(dian)(dian)(dian)(dian)子陶瓷(ci)的(de)主要(yao)導電(dian)(dian)(dian)(dian)方(fang)式。