一、陰極銅是什么意思
金(jin)屬銅(tong)元素(su)符號Cu,原子量63.55,比重8.96,熔點(dian)1083.4士0.2°℃,沸點(dian)2567°℃。銅(tong)呈淺玫瑰色(se)(se)或(huo)淡紅色(se)(se),表面形成氧化銅(tong)膜后,外觀呈紫銅(tong)色(se)(se),是人類最早發(fa)現的古老金(jin)屬之—。
陰極銅(copper cathode)是指銅(tong)精(jing)(jing)礦由電解精(jing)(jing)煉(lian)法(fa)或電解沉積法(fa)生產得到的(de)(de)高純度的(de)(de)銅(tong),也(ye)稱精(jing)(jing)煉(lian)銅(tong)或精(jing)(jing)銅(tong)(refinedcopper)。國標(biao)GB/T 467-2010、歐標(biao)BS EN 1978-1998和美標(biao)ASTM B115均(jun)是陰極銅(tong)的(de)(de)行業標(biao)準規(gui)范。
由于陰極(ji)銅(tong)具(ju)有(you)(you)較優(you)良的導電(dian)性(xing)、導熱性(xing)、延展性(xing)、耐腐蝕性(xing)、耐磨性(xing)等特點,因此陰極(ji)銅(tong)被下游加工(gong)成銅(tong)線、銅(tong)棒、銅(tong)板帶、銅(tong)箔、銅(tong)管以及各類(lei)合金產品,被廣泛應用于電(dian)力、電(dian)子、交通設備(bei)、機(ji)械制造、建筑工(gong)業(ye)、國(guo)防工(gong)業(ye)、醫學(xue)、有(you)(you)機(ji)化學(xue)等行業(ye),在我國(guo)有(you)(you)色金屬材料的消費中僅次(ci)于鋁。
二、陰極銅和電解銅的區別
電(dian)解銅(tong)和(he)陰極銅(tong)沒有區別。
陰(yin)極(ji)銅(tong)(tong)(tong)(tong)(tong)通常指(zhi)電(dian)(dian)解(jie)(jie)(jie)(jie)銅(tong)(tong)(tong)(tong)(tong),就是指(zhi)將粗(cu)銅(tong)(tong)(tong)(tong)(tong)(含銅(tong)(tong)(tong)(tong)(tong)99%)預先制成厚(hou)板作(zuo)(zuo)為(wei)陽極(ji),純(chun)銅(tong)(tong)(tong)(tong)(tong)制成薄(bo)片作(zuo)(zuo)陰(yin)極(ji),以硫酸(suan)和(he)(he)硫酸(suan)銅(tong)(tong)(tong)(tong)(tong)的(de)混合液作(zuo)(zuo)為(wei)電(dian)(dian)解(jie)(jie)(jie)(jie)液。通電(dian)(dian)后,銅(tong)(tong)(tong)(tong)(tong)從陽極(ji)溶解(jie)(jie)(jie)(jie)成銅(tong)(tong)(tong)(tong)(tong)離(li)子(zi)(Cu)向陰(yin)極(ji)移動,到達(da)陰(yin)極(ji)后獲得電(dian)(dian)子(zi)而在陰(yin)極(ji)析出純(chun)銅(tong)(tong)(tong)(tong)(tong)(亦稱電(dian)(dian)解(jie)(jie)(jie)(jie)銅(tong)(tong)(tong)(tong)(tong))。粗(cu)銅(tong)(tong)(tong)(tong)(tong)中雜質(zhi)如比銅(tong)(tong)(tong)(tong)(tong)活潑(po)的(de)鐵和(he)(he)鋅(xin)等會隨銅(tong)(tong)(tong)(tong)(tong)一起(qi)溶解(jie)(jie)(jie)(jie)為(wei)離(li)子(zi)(Zn和(he)(he)Fe)。由于這些離(li)子(zi)與銅(tong)(tong)(tong)(tong)(tong)離(li)子(zi)相比不(bu)易析出,所以電(dian)(dian)解(jie)(jie)(jie)(jie)時(shi)只(zhi)要適當調節電(dian)(dian)位差(cha)即可避(bi)免這些離(li)子(zi)在陰(yin)極(ji)上析出。比銅(tong)(tong)(tong)(tong)(tong)不(bu)活潑(po)的(de)雜質(zhi)如金和(he)(he)銀等沉積在電(dian)(dian)解(jie)(jie)(jie)(jie)槽的(de)底部(bu)。這樣(yang)生(sheng)產出來的(de)銅(tong)(tong)(tong)(tong)(tong)板,稱為(wei)“電(dian)(dian)解(jie)(jie)(jie)(jie)銅(tong)(tong)(tong)(tong)(tong)”,質(zhi)量極(ji)高(gao),可以用來制作(zuo)(zuo)電(dian)(dian)氣產品。
陰極(ji)(ji)銅的品質要(yao)求:銅精礦(kuang)由(you)電解精煉法(fa)或電解沉積法(fa)生產得到(dao)陰極(ji)(ji)銅。按國標(biao)(biao)GB/T467-1997《陰極(ji)(ji)銅》的規(gui)定(ding),陰極(ji)(ji)銅按化學成分分為高純陰極(ji)(ji)銅(Cu-CATH-1)和標(biao)(biao)準(zhun)陰極(ji)(ji)銅(Cu-CATH-2)和兩個牌(pai)號。
陰極銅的(de)(de)試驗方(fang)法:高純陰極銅(tong)化學(xue)成分的(de)(de)仲(zhong)(zhong)裁(cai)分析(xi)方(fang)法按(an)GB/T13293-1991《高純陽極銅(tong)化學(xue)分析(xi)方(fang)法》的(de)(de)規定進行,標準陰極銅(tong)化學(xue)成分的(de)(de)仲(zhong)(zhong)裁(cai)分析(xi)方(fang)法按(an)GB/T5121-1996《銅(tong)及銅(tong)合金化學(xue)分析(xi)方(fang)法》的(de)(de)規定進行。表面(mian)質量用目視檢測(ce)。