一、電子陶瓷是絕緣體還是導體
一般認(ren)為(wei),陶(tao)瓷是良好的(de)(de)絕(jue)緣體(ti),它一般不(bu)導(dao)(dao)電(dian),因(yin)為(wei)原子(zi)的(de)(de)外層電(dian)子(zi)通常(chang)受到原子(zi)核的(de)(de)吸引力,被束縛在各(ge)自(zi)原子(zi)的(de)(de)周圍,不(bu)能自(zi)由(you)運動,不(bu)過電(dian)子(zi)陶(tao)瓷具有極為(wei)寬廣(guang)的(de)(de)電(dian)氣特性,從(cong)一般的(de)(de)絕(jue)緣體(ti),到半導(dao)(dao)體(ti),導(dao)(dao)體(ti)、甚至超(chao)導(dao)(dao)體(ti),都有不(bu)同的(de)(de)電(dian)子(zi)陶(tao)瓷產品。
電(dian)子陶瓷(ci)(ci)的(de)種(zhong)(zhong)類眾多(duo),其(qi)中(zhong)絕緣陶瓷(ci)(ci)裝置瓷(ci)(ci)和介電(dian)陶瓷(ci)(ci)是(shi)絕緣體(ti)(ti)(ti),半(ban)導(dao)體(ti)(ti)(ti)陶瓷(ci)(ci)是(shi)半(ban)導(dao)體(ti)(ti)(ti),離子陶瓷(ci)(ci)是(shi)導(dao)體(ti)(ti)(ti),還有一(yi)種(zhong)(zhong)超導(dao)陶瓷(ci)(ci)屬于超導(dao)體(ti)(ti)(ti)。
二、電子陶瓷導電原理是什么
電子陶瓷有的導電,有的不導電,導電的電子陶瓷一般是通過一定的工(gong)藝(yi)處理(li),使其(qi)具有導電功能的。
某(mou)些氧化物陶瓷加熱時,處于原子外層的(de)(de)電子可以(yi)獲得足夠的(de)(de)能量,以(yi)便克(ke)服原子核對它的(de)(de)吸引力,而成為可以(yi)自由(you)運動(dong)的(de)(de)自由(you)電子,這種(zhong)陶瓷就變(bian)成導電陶瓷。
一般(ban)當電(dian)(dian)(dian)流(liu)通過材(cai)料時,電(dian)(dian)(dian)子(zi)(zi)(zi)(zi)可(ke)以有兩種(zhong)方式通過晶格運(yun)動(dong)(dong)來(lai)完成(cheng)電(dian)(dian)(dian)荷(he)輸運(yun)過程:①電(dian)(dian)(dian)子(zi)(zi)(zi)(zi)脫離(li)原子(zi)(zi)(zi)(zi)成(cheng)為自由(you)電(dian)(dian)(dian)子(zi)(zi)(zi)(zi),在(zai)晶格中運(yun)動(dong)(dong),形成(cheng)所(suo)(suo)謂的電(dian)(dian)(dian)子(zi)(zi)(zi)(zi)導(dao)電(dian)(dian)(dian);②電(dian)(dian)(dian)子(zi)(zi)(zi)(zi)與(yu)原子(zi)(zi)(zi)(zi)核一起移動(dong)(dong)產生所(suo)(suo)謂的離(li)子(zi)(zi)(zi)(zi)導(dao)電(dian)(dian)(dian)。對金(jin)屬來(lai)說(shuo),電(dian)(dian)(dian)子(zi)(zi)(zi)(zi)導(dao)電(dian)(dian)(dian)是(shi)其導(dao)電(dian)(dian)(dian)的主(zhu)要(yao)方式,相比(bi)之下(xia),離(li)子(zi)(zi)(zi)(zi)導(dao)電(dian)(dian)(dian)幾乎可(ke)忽略不計;但對于(yu)導(dao)電(dian)(dian)(dian)電(dian)(dian)(dian)子(zi)(zi)(zi)(zi)陶瓷來(lai)說(shuo),由(you)于(yu)離(li)子(zi)(zi)(zi)(zi)電(dian)(dian)(dian)導(dao)活化(hua)能(neng)比(bi)較低(一般(ban)在(zai)0.5eV以下(xia)),離(li)子(zi)(zi)(zi)(zi)導(dao)電(dian)(dian)(dian)已不容(rong)忽視,是(shi)電(dian)(dian)(dian)子(zi)(zi)(zi)(zi)陶瓷的主(zhu)要(yao)導(dao)電(dian)(dian)(dian)方式。